1. Match List-I with List-II

Choose the correct answer from the options given below:

(1).A-I, B=II, C-III, D-IV

(2). A-II, B-III, C-IV. D-I

(3). A-IV, B-III, C-II, D-I

(4). A-IV, B-II, C-III, D-I

2. In which of the following processes entropy form increases ?

(1).A liquid evaporates to vapour

(2). Temperature of a crystalline solid lowered from 130 K to 0 K

(3). \(2\text{NaHCO}_3\left(g\right)\,\rightarrow\,\text{Na}_2\text{CO}_3\left(s\right)\,+\,\text{CO}_2\left(g\right)\,+\,\text{H}_2\text{O}\left(g\right)\)

(4). \( \text{Cl}_2(g) \rightarrow 2\text{Cl}(g) \)

3. The work done during reversible isothermal expansion of one mole of hydrogen gas at \(25^\circ \text{C}\) from pressure of \(20\) atmosphere to \(10\) atmosphere is:
(Given \(\text{R}\,=\,2.0\,cal K^{-1}mol^{-1}\))

(1).413.14 calories

(2). 100 calories

(3). 0 calorie

(4). -413.14 calories

4. The standard heat of formation, in kcal/mol of \(Ba^{2+}\) is: [Given : standard heat of formation of \(\text{So}^{2-}_4 ion (aq) = - 216 kcal/mol, standard heat of crystallisation of \(\text{BaSO}_4(s) = - 4.5 kcal/mol, standard heat of formation of \(\text{ BaSO}_4(s) = - 349 kcal/mol]

(1).+ 220.5

(2). - 128.5

(3). - 133.0

(4). + 133.0

5. \(C(s) + 2H_2\left(g\right) \rightarrow CH₄(g);\Delta H = -74.8 kJ mol^{-l}\) Which of the following diagrams gives an accurate representation of the above reaction? [R → reactants; P → products]

(1).

(2).

(3).

(4).